Zr/Hf ratio as an indicator of fractionation of rare-metal granites by the example of the Kukulbei complex,eastern Transbaikalia     

G. P. Zaraisky  A. M. Aksyuk  V. N. Devyatova  O. V. Udoratina  V. Yu. Chevychelov 《Petrology》2008,16(7):710-736

The concept of granitic melt fractionation as the main process in the concentration of rare elements in granites calls for the development of a reliable method to determine the evolutionary sequences of granite series. We propose to use for this purpose a zirconium-hafnium indicator, the Zr/Hf weight ratio in granitic rocks (Zaraisky et al., 1999, 2000). By the example of three classic regions of rare-metal deposits, eastern Transbaikalia, central Kazakhstan, and Erzgebirge (Czech Republic and Germany), it was empirically shown that the Zr/Hf ratio of granites decreases during the fractional crystallization of granite magmas in the sequence granodiorite → biotite granite → leucogranite → lithium-fluorine granite. The reason is the higher affinity of Hf compared with Zr to a granite melt. This implies that the crystallization and settling of accessory zircon will cause the progressive enrichment of Hf relative to Zr in the residual melt. As a result, the Zr/Hf ratio decreases regularly in the series of sequential phases of granite intrusion related to a single magma chamber from granodiorite to biotite granite, leucogranite, and Li-F granite (from 45-30 to 10-2). Our experimental investigations supported the preferential enrichment of haplogranite melt in Hf and zircon crystals in equilibrium with melt in Zr (T= 800°C and P = 1 kbar). The Zr/Hf indicator was tested by the example of the wellknown Kukulbei rare-metal granite complex of eastern Transbaikalia (J3), which is unique in the degree of fractionation of initial granite melt with the formation of three phases of granite emplacement and vein derivatives. An important feature of the complex is its “short” differentiation trend. It was supposed that the granite magma of the first phase is parental, and the later phases forming small intrusive bodies in large massifs of biotite granites of the first phase are sequential products of its crystallization differentiation in a magma chamber. The biotite granites of the first phase are barren. The leucocratic granites of the second phase are accompanied by tin-tungsten greisen deposits (e.g., Spokoininskoe), and the upper part of cupola-like stocks of Li-F amazonite granites of the third phase host apogranite-type tantalum deposits (Orlovka, Etyka, and Achikan). In addition to three granite phases, the Kukulbei complex includes dikes of ongonites, elvans, amazonite granites, and chamber miarolitic pegmatites. All of the granitic rocks of the complex have similar isotopic ages of 142± 0.6 Ma. The Zr/Hf ratio decreases systematically from phase 1 (40–25), to phase 2 (20–10), and phase 3 (10–2). The ongonites, elvans, and pegmatites have similar Zr/Hf ratios (15-5), falling between the ranges of leucocratic muscovite granites and Li-F granites. Compared with other granite series, the granitic rocks of the Kukulbei complex show specific petrographic and geochemical features: they are strongly enriched in Rb, Li, Cs, Be, Sn, W, Mo, Ta, Nb, Bi, and F but depleted in Mg, Ca, Fe, Ti, P, Sr, Ba, V, Co, Ni, Cr, Zr, REE, and Y. From the early to late intrusion phases, the degree of enrichment and depletion in these element groups increases regularly. This is accompanied by a significant decrease (from 40 to 2) in Zr/Hf, which can be used as a reliable indicator of genetic relations, degree of fractionation, and rare-metal potential of granites. Granites with Zr/Hf values lower than 25 are promising for prospecting for Sn, W, Mo, and Be greisen deposits, whereas the formation of Ta deposits requires Zr/Hf values lower than 10.  相似文献   

Opacitization conditions of hornblende in Bezymyannyi volcano andesites (March 30, 1956 eruption)     

P. Yu. Plechov  A. E. Tsai  V. D. Shcherbakov  O. V. Dirksen 《Petrology》2008,16(1):19-35

The paper is devoted to the conditions under which opacite rims developed around hornblende grains in andesite of the catastrophic eruption (March 30, 1956) of Bezymyannyi volcano, Kamchatka. The opacite rims were produced by a bimetasomatic reaction between hornblende and melt with the development of the following zoning: hornblende → Px + Pl + Ti-Mag → Px + Pl → Px → melt. Biometasomatic reaction was accompanied by the active removal of CaO from the rim, addition of SiO₂, and more complicated behavior of other components. The hornblende also shows reactions of its volumetric decomposition under near-isochemical conditions. The opacite rims developed under isobaric conditions, at a pressure of approximately 6 kbar. The main reason for the instability of the hornblende was the heating of the magma chamber from 890 to 1005°C due to new hot magma portion injection. The time interval between the injection and the start of eruption was estimated from the thickness of the opacite rims and did not exceed 37 days. Hence, the March 30, 1956, eruption was not related to the volcanic activity in November of 1955 but to the injection of a fresh magma portion in February–March of 1956.  相似文献   

Biogeochemical characteristics of the Hetai goldfield, Guangdong Province, China     

Li Miao  Ruisong Xu  Yueliang Ma  Jinhong Xu  Jie Wang  Rui Cai  Yu Chen   《Journal of Geochemical Exploration》2008,96(1):43-52

In the Hetai goldfield, Guangdong Province, China, samples including rocks, soils and leaves of four plants (Pinus massoniana, Rhodomyrms tomenlosa, D. linearis var. dichotoma and Embelia laeta) collected from the gold mineralization zone and the background area were analyzed for Au, Ag, Cu, Pb, Zn, Hg, As and physiological parameters. The objective of this investigation is to study the geochemical and biogeochemical characteristics of studied plants, aiming at biogeochemical methods in Au exploration. The goldfield region shows geochemical and biogeochemical anomalies. Abundances of Au in rocks, soils, plants and the leaf pigments in the mineralized area are much higher than those in the surrounding region. The plants display unhealthy physiological and ecological characteristics in the Hetai goldfield area. The cell structures of the goldfield plants were anomalous and aberrant, and there were many nano-metal particles diffused in mitochondria and chloroplasts. Macro- and microscopic evidences of the vegetation in the goldfield areas are distinctly different from the background regions. The strongly anomalies in responses to Au are profound in further geochemical and botanic exploration studies.  相似文献   

云南罗平中三叠世安尼期生物群的发现及其意义   总被引：15，自引：0，他引：15  

张启跃  周长勇  吕涛  谢韬  楼雄英  刘伟  孙媛媛  江新胜 《地质论评》2008,54(4):523-526

本文介绍了云南罗平地区新发现的罗平生物群的产出层位、生物面貌、保存特征、古地理位置及其研究意义。该生物群产于关岭组二段薄层泥晶灰岩中,地层对比和化石鉴定表明其时代为中三叠世安尼期,以鱼类为主,伴生有爬行类、两栖类（？）、棘皮动物、节肢动物（甲壳类、昆虫等）、双壳类、腹足类以及植物化石;化石保存完好,分布广泛,埋藏方式独特。罗平生物群无论在丰度、分异度及化石保存上都极为罕见和独特,对研究埋藏学、古生态学、古地理以及三叠纪海洋生物尤其是海生爬行类都具有极为重要的意义。  相似文献   

松辽盆地三肇凹陷葡萄花油层成藏模式初探   总被引：11，自引：5，他引：6       下载免费PDF全文

孙雨  马世忠  刘云燕  刘宗堡  于利民 《地质科学》2008,43(4):746-757

运用源控含油气系统理论与综合分析技术,按成藏“层次分析”方法,通过对生、储、盖、圈(闭)静态要素及其内生、排、运、聚、散(失)动态过程的综合研究,对松辽盆地中央坳陷的三肇凹陷葡萄花油层成藏条件进行探讨,提出了以次级凹陷为中心、不同类型的油气聚集带紧邻并围绕次级凹陷最低部位呈环带状分布的大型凹陷内成藏模式,并进一步提出永乐次级凹陷中心及其三级聚油环带及徐家围子次级凹陷以西为"网式"运聚特征;在凹陷级成藏模式的指导下,通过对大面积密井网开发区综合解剖,提出三级构造带中单个的局部构造圈闭(群)、单个的(局部构造——)岩性圈闭(群)控油和成藏规律,为认识本区基本控油单元、油水分布规律、油气勘探及扩大新探区提供重要的理论依据。  相似文献   

祁连山首次发现冰楔假形及其意义   总被引：2，自引：2，他引：0  

吴吉春  孙立平  盛煜  吴青柏  李金平 《冰川冻土》2008,30(4)

2007年11月, 在祁连山东段南坡大通河上游河谷右岸的取土坑内(37°51′ N, 100°08′ E;海拔3 618 m)首次发现楔形构造, 成群分布在表层草根腐殖土之下约0.5 m深度处. 楔体呈袋状或舌状, 楔口宽度和楔体高度约在2.0～3.0 m, 宽高比值接近1. 楔体周围地层为冲洪积相碎石土堆积, 充填物为土黄色、灰黑色粉质土. 楔体两壁附近的卵、碎石长轴具有平行于楔壁的定向性, 说明这些碎石曾经受到过挤压, 据此初步判断这些楔形构造为冰楔假形. 这些冰楔假形发现对于研究该地区冻土演化和古气候具有参考意义.  相似文献   

中国-俄罗斯原油管道工程(漠河-大庆段)冻土工程地质考察与研究进展   总被引：4，自引：2，他引：2  

李国玉  金会军  盛煜  张建明  俞祁浩  齐吉琳  温智  吕兰芝  童长江  郭东信  王绍令  魏智  杨思忠  吉延俊  于少鹏  何瑞霞  常晓丽  郝加前  陈友昌  吴伟  翟镇远  赵意民 《冰川冻土》2008,30(1):170-175

在2005-2007年期间,先后3次对中国-俄罗斯原油管道漠河-大庆段沿线的冻土工程地质条件等进行科学考察,开展了冻土工程地质条件及其在气候变化和人类活动作用下的评价和预测研究.考察研究结果表明:管道沿线多年冻土在各类融区、季节冻土和水系等分隔作用下呈片状或岛状分布,沿线岛状、稀疏岛状及零星岛状占多年冻土区段的40%左右;管道沿线多年冻土随着气候的转暖和人类活动的影响不断退化.地形地貌单元、植被分布、地表水分条件的变化等局部因素对多年冻土的分布和地下冰的赋存产生重要的影响,管道沿线大约分布有50 km左右的沼泽湿地,其表层为腐殖质土及泥炭层,泥炭层下面分布着含土冰层或地下冰,是管道沿线最差的冻土工程地质地段;由于中俄原油管道沿线水系发育多,冻胀丘、冰椎和冰幔等不良冻土现象广泛分布.科学考察的成果为管道沿线冻土工程地质条件评价和预测、管道的稳定性影响分析以及后期的长期检测系统设置等研究奠定坚实的基础,进一步为即将开工的中俄原油管道漠河-大庆段工程的设计、施工提供科学依据.  相似文献   

黑龙江省金厂金矿床J0矿体流体地球化学研究   总被引：7，自引：6，他引：1  

张宇  赖勇  卿敏  王艳忠  徐佳佳 《岩石学报》2008,24(5)

黑龙江省东宁县金厂金矿床是最新发现的特大型金矿床,目前探获黄金资源量86吨,它位于中亚造山带东端的吉黑成矿带,是与中生代中酸性岩浆活动有关的复杂成矿系统,矿化类型可能包括了斑岩型、爆破角砾岩型、浅成低温热液型.研究表明,高丽沟J0号矿体为爆破角砾岩型,热液成矿过程经历了早、中、晚3个阶段,分别形成以石英-黄铁矿、多金属硫化物-石英和碳酸盐为代表的矿物组合,中阶段矿物含自然金最多,次为早阶段矿物.初始成矿流体系统为高温、高盐度、高氧逸度、富CO2的岩浆热液;经减压沸腾,CO2等挥发分大量逸出,流体温度、盐度和氧逸度下降,导致大量金属硫化物及自然金快速沉淀;大气降水混入导致晚阶段流体低温、低盐度、贫CO2,对成矿贡献甚微.总体而言,成矿流体盐度高(11.70%～37.81%NaCl.eq),成矿作用发生在中-高温(238.3～425.7℃)的浅成环境(深633m～2736m).岩浆-流体成矿系统富CO2应发育于大陆碰撞造山带的伸展构造背景,而非大洋板块俯冲诱发的岩浆弧背景.  相似文献   

河南洛宁段河金矿流体包裹体研究和矿床成因   总被引：2，自引：1，他引：1  

赖勇张宇高栏  李文博 《中国地质》2008,35(6):1206-1219

河南省洛宁县段河石英脉型金矿主要包括石寨沟和岭东两个矿区,分别由3～4条含金石英脉构成。矿化过程从早到晚包括石英-黄铁矿、石英-多金属硫化物和石英-碳酸盐等3个阶段．其中中阶段金矿化最强,次为早阶段。各阶段石英中流体包裹体以气液两相包裹体为主．次为纯液体包裹体。激光拉曼测试表明,气液两相包裹体的液相为H2O,气相主要为Ho和CO2混合、纯H2O,次为纯CO2;纯液体包裹体为纯H2O。石寨沟矿区包裹体均一温度从早到晚依次为240．9～315．9℃．188．7～304．5℃,137．3～259．3℃：流体盐度变化依次为（6．74～12．85）wt%NaCl．eq,（2．41～8．68）wt％NaCl．eq,（2．24-7．86）wt%NaCl．eq。岭东矿区均一温度从早到晚依次为303．7-343．1℃,251．8-325．4℃,305．7～355．0℃：流体盐度变化依次为（5．11～11．70）wt％NaCl．eq,（2．74-10．11）wt％NaCl．eq,（0．53-6．74）wt％NaCl．eq。两矿区主成矿期流体均为中温、低盐度,早阶段流体为改造热液和变质热液的混合体,含一定量CO2,且流体CO2含量和盐度从早到晚逐渐降低。石寨沟矿区包裹体均一温度逐渐降低,而岭东矿区包裹体均一温度先降后升,加之岭东矿区各阶段成矿温度均高于石寨沟矿区．表明成矿流体系统主要受岩浆热驱动,岭东矿区更靠近岩体,且在晚阶段又有脉动性的岩浆加热．段河金矿区南部存在隐伏岩体。  相似文献   

利用InSAR技术研究黄土地区滑坡分布   总被引：1，自引：0，他引：1  

程滔  单新建  董文彤  李建华 《水文地质工程地质》2008,35(1):98-101

InSAR技术能够获取大面积、连续、高精度的地表垂直形变信息,可用来监测地震、火山、滑坡等自然灾害造成的地表形变。文章介绍了InSAR技术在监测陕北黄土地区滑坡中的应用,首先进行野外地质勘察和TM光学遥感影像解译,接着通过EnviSat SAR数据差分干涉处理,获取研究区干涉形变场,提取出滑坡位移量,最后详细分析黄草湾至董家寺沿线一带的滑坡变形范围,并划定出了4个有一定变形的重点监视区。  相似文献